Experimental bond dissociation energies of benzylpyridinium thermometer ions determined by threshold-CID and RRKM modeling
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چکیده
منابع مشابه
Bond dissociation energies
The bond dissociation energy (enthalpy) is also referred to as bond disruption energy, bond energy, bond strength, or binding energy (abbreviation: BDE, BE, or D) . It is defined as the standard enthalpy change of the following fission: R−X → R + X . The BDE, denoted by Do(R−X), is usually derived by the thermochemical equation, Do(R−X) = ∆fH o(R) + ∆fH o(X) – ∆fH o(RX) . The enthalpy of format...
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In this Account we have compiled a list of reliable bond energies that are based on a set of critically evaluated experiments. A brief description of the three most important experimental techniques for measuring bond energies is provided. We demonstrate how these experimental data can be applied to yield the heats of formation of organic radicals and the bond enthalpies of more than 100 repres...
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ژورنال
عنوان ژورنال: International Journal of Mass Spectrometry
سال: 2017
ISSN: 1387-3806
DOI: 10.1016/j.ijms.2017.03.002